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This bothers me a lot, probably because I just fail to understand some basic mathematical principle that textbooks think too obvious to mention.
Go to any textbook about thermodynamic potentials and you'll read something like this:
Book:
>Want to evaluate the spontaneity of a system at constant temperature and pressure? You need the Gibbs Energy.
>dG = -SdT + VdP
Me:
>Wait, it can't be constant T and P because both terms would always be zero.
The same argument can be made for other potentials which the textbook says hold a pair of natural variables constant.
This seems like an obvious contradiction to me, but the textbooks never mention it.
Go to any textbook about thermodynamic potentials and you'll read something like this:
Book:
>Want to evaluate the spontaneity of a system at constant temperature and pressure? You need the Gibbs Energy.
>dG = -SdT + VdP
Me:
>Wait, it can't be constant T and P because both terms would always be zero.
The same argument can be made for other potentials which the textbook says hold a pair of natural variables constant.
This seems like an obvious contradiction to me, but the textbooks never mention it.
